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On the stereochemistry of reduction of 9-methyl-1-carboxy-Δ4-3-octalone: A remarkable lithium-ammonia reduction

✍ Scribed by John E. McMurry; Larry C. Blaszczak; Mark A. Johnson


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
117 KB
Volume
19
Category
Article
ISSN
0040-4039

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## Abstract Reduction of the α,β‐unsaturated lactone system in 1‐hydroxy‐3‐pentyl‐7,8‐dihydro‐spiro[dibenzo[b,d]pyran‐9,2′‐[1,3]dioxolan]‐6(10H)‐one (3) with lithium in liquid ammonia leads to cis products.