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Novel Stereochemical results in the birch reduction of 4-alkyl-Δ1(9)-2-octalones

✍ Scribed by Edward Piers; Wynona M. Phillips-Johnson; Christian Berger

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 192 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)84971-6

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Non-stereoselectivity in reductive alkylation of Δ1,9-2-octalones

✍ P.T. Lansbury; G.E. DuBois 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 194 KB

Stereoselective reductive methylation of polycyclic enones of the l-alkyl-A&' -2-octalone variety has been used advantageously by Stork et al in total syn--theses of steroids' and the triterpene lupeo12. Matthews3 has also examined