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Photochemical, acid, and base catalyzed rearrangement of 5,10-dimethyl-5-hydroxy-Δ1,9 -2-octalone

✍ Scribed by D. Gravel; J. Gauthier

Book ID: 104222999
Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 317 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89810-x

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✦ Synopsis

A recent communication by Schuster and Brizzolara (1) prompts us to report our results on the investigation of the photochemical rearrangement of 5,10-dimethyl-5-hydroxy-A lV9-2-octalone (1). In studying the photochemistry of compound 1, it was hoped that the presence of a hydroxyl group in an appropriate position would alter the course of the normal enone rearx'angement and perhaps yield information as to the type of intermediate involved in these reactions.

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