𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Non-equilibrium kinetics of bimolecular reactions. Effect of anharmonicity on the rate law

✍ Scribed by Heshel Teitelbaum

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
533 KB
Volume
202
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Effect of reagent density fluctuations o
Effect of reagent density fluctuations on bimolecular reaction kinetics
✍ V.N. Kuzovkov; E.A. Kotomin πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 English βš– 314 KB

The pccuhwnics oithe kineucsoT3 blmolccular re3ctlon A + B -C cwwd by non-Poluon fluctuations of rcgunt dcn-511~s spon~ancously produced durmg a dnIusioncon~roUcd rcxtlon xc mdyscd. The 3symptollc long-time Lmcucs IS predlcted to bc n c: I-"' (for qua reqent concentmt~ons) contrzuy LO :he or&nary lw

Steric Effects on Reaction Rates. Rate a
Steric Effects on Reaction Rates. Rate and equilibrium constants for oxidation of cyclanols
✍ Paul MΓΌller; Jacky Blanc πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 German βš– 393 KB πŸ‘ 2 views

## Abstract Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Ξ”__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for

Effectiveness factors for the general no
Effectiveness factors for the general non-isothermal case of bimolecular Langmuir-Hinshelwood kinetics
✍ Samuel H. Wong; Stephen SzΓ©pe πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 English βš– 457 KB

Non-isothermal catalyst effectiveness factors are determined for both exothermic and endothermic reactions with rate equations of the form r, = /&,,/(I + K,,CJ'. It is shown that with such rate equations, multiplicities may occur even for endothermic reactions. In addition, multiple states may arise

Effects of non-equilibrium corrections t
Effects of non-equilibrium corrections to rate coefficients on stability of reacting systems
✍ Kin-Wah Li; Byung C. Eu πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 460 KB

in this paper we re-examine the couplcd rate equations represcntative of coupled chemical reactions with an cxamplc of the Volterra-Lotka type model. We find that unlike in the previous analysis of stability of such systems, if we take into account the non-equilibrium corrections to the rate coeffΓ­c