Classical trajectory c~cu~ations on fi + H&3 reactions have been carried out. At few collision ener$es the reaction cross section decreases for smnU j. reaching 3 minimum at j = 4, then increases as j increases. It isdso shown rbat rhe isotopic branching ratio is fairly sensitive xo reagent rotation
Effect of reagent density fluctuations on bimolecular reaction kinetics
β Scribed by V.N. Kuzovkov; E.A. Kotomin
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 314 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The pccuhwnics oithe kineucsoT3 blmolccular re3ctlon A + B -C cwwd by non-Poluon fluctuations of rcgunt dcn-511~s spon~ancously produced durmg a dnIusioncon~roUcd rcxtlon xc mdyscd. The 3symptollc long-time Lmcucs IS predlcted to bc n c: I-"' (for qua reqent concentmt~ons) contrzuy LO :he or&nary lw of fomxd chcnucat kmctlcs,r = I-'.
π SIMILAR VOLUMES
With the exception of work by Goto et al., all these earlier studies considered only a bimolecular reaction with pseudofirst-order kinetics; i.e., first order with respect to the limiting reactant and zero order for the excess reactant. Goto et al. used pseudo-nth-order kinetics. Recently, Beaudry e
S~~~YIUI~ from the generalized theory of blmolwlar diffusion-controlled reactiorus betwatn reagents in soli& and liquids, we have performed calculations of Lhe A+B \* AB (F'renkel defecL anmhilalion) and A+A + B (exciton annihdation) reaction kinetics over a wide time interval and for high initial c
The effects of chain-length of the diols and aliphatic dicarboxylic acids on the rate of polyesterification were studied. It was shown that the rate is only slightly influenced by the chain-length of the dicarboxylic acid. On the contrary, the reaction rate increases considerably with the chainlengt