𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Many-particle effects in kinetics of bimolecular diffusion-controlled reactions

✍ Scribed by E. Kotomin; V. Kuzovkov

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
399 KB
Volume
117
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

S~~~YIUI~ from the generalized theory of blmolwlar diffusion-controlled reactiorus betwatn reagents in soli& and liquids, we have performed calculations of Lhe A+B * AB (F'renkel defecL anmhilalion) and A+A + B (exciton annihdation) reaction kinetics over a wide time interval and for high initial concentrations The prtdickd lowering at long times of the reaction rate in Lhc course of the A+B -D AB reaction and acceleration at short times of the A+A +B reaction due to dynamical aggregation of similar non-interacting reagenls are demonstrated_ The posubility of experimental checks of these effecLs IS

πŸ“œ SIMILAR VOLUMES

Kinetic Approach to Reaction and Diffusi
Kinetic Approach to Reaction and Diffusion in Many-Particle Systems
✍ Yu. L. Klimontovich; M. Schlanges; T. Bornath πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 948 KB

## Abstract A derivation of hydrodynamic equations which describe diffusion in connection with reaction processes in many‐particle systems is given on the basis of quantum kinetic theory. For this purpose kinetic equations are derived for a quantum gas with chemical reactions. Following Grad's meth

Kinetics of partly diffusion-controlled
Kinetics of partly diffusion-controlled reactions. XIV. Effects of reversible energy transfer
✍ R. Guillard; J. C. Andre; M. Bouchy πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 English βš– 479 KB

The general effect of back energy transfer is to reduce the apparent quenching constant which is an important parameter in the interpretation of energy transfer data. However, this interpretation may be erroneous when possible diffusion effects and the existence of nonuniform configurational distrib

A study of fluorescence quenching in hom
A study of fluorescence quenching in homomicelles and mixed micelles analyzed by diffusion-controlled and fractal reaction model kinetics
✍ M.M. VelΓ‘zquez; SΓ­lvia M.B. Costa πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 437 KB

Fluorescence data-emission intensities and decay profiles of benzyl 1-pyrenoate in the presence of dimethylaniline in anionic homomicelles and in mixed micelles have been analyzed with two different models: a kinetic model of diffusion-controlled reactions in micelles with a reflecting boundary surf