S~~~YIUI~ from the generalized theory of blmolwlar diffusion-controlled reactiorus betwatn reagents in soli& and liquids, we have performed calculations of Lhe A+B \* AB (F'renkel defecL anmhilalion) and A+A + B (exciton annihdation) reaction kinetics over a wide time interval and for high initial c
Kinetic Approach to Reaction and Diffusion in Many-Particle Systems
β Scribed by Yu. L. Klimontovich; M. Schlanges; T. Bornath
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 948 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0005-8025
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β¦ Synopsis
Abstract
A derivation of hydrodynamic equations which describe diffusion in connection with reaction processes in manyβparticle systems is given on the basis of quantum kinetic theory. For this purpose kinetic equations are derived for a quantum gas with chemical reactions. Following Grad's method in a linear approximation reactionβdiffusion equations can be obtained with explicite expressions for the diffusion and reaction rate coefficients. The influence of nonideality effects in reactionβdiffusion equations is discussed.
π SIMILAR VOLUMES
A numerical approach to modeling a biochemical system that includes processes with significantly different time scales has been developed within the Virtual Cell environment (J. Schaff et al., 1997, Biophys. J. 73, 1135). The key features of the algorithm are time splitting of slow and fast processe