Non-classical free-radical polymerization: 3. Diffusion-control in degradative addition
โ Scribed by C.H Bamford; E Schofield
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 528 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0032-3861
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Highโresolution free radical polymerization kinetics was obtained using automatic continuous online monitoring of polymerization reactions (ACOMP). A sharp crossโover from diffusionโcontrolled initiation at low [monomer] to initiator decomposition control at higher [monomer] was found,
5-Bromopenta-1,3-diene (BPD) was examined as an additionfragmentation chain transfer agent (AFCTA) in the free radical polymerization of methyl methacrylate (MMA). Studies of the kinetics of polymerization in the presence of this compound showed it to be a very e โ ective chain transfer agent and tha