Non-classical free-radical polymerization: Degradative addition to monomer in the polymerization of 1-vinylimidazole
โ Scribed by C.H. Bamford; E. Schofield
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 729 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0032-3861
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๐ SIMILAR VOLUMES
## Abstract **Summary:** A detailed investigation of chain transfer to polymer during free radical ringโopening polymerization of the eightโmembered disulfide monomer 2โmethylโ7โmethyleneโ1,5โdithiacyclooctane (MDTO) is presented. It has been shown that extensive chain transfer to polymer occurs in
Ethyl 2-[ 1-(trimethylsilylperoxy)ethyl]propenoate 1, ethyl 2-[ 1-(dimethylvinylsilylperoxy)ethyllpropenoate 2, ethyl 2-[ 1-( l-(2-ethoxycarbonyl-l-methyl-2-propenylperoxysilyl)-l-methylethylperoxy)ethyl]propenoate 3, and 2-phenyl-2-trimethylsilylperoxypropane 4 were synthesized and added to the fre