Addition-fragmentation of 5-bromopenta-1,3-diene in free radical polymerization of methyl methacrylate

✍ Scribed by Reghunadhan Nair, C. P.

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 233 KB
• Volume: 46
• Category: Article
• ISSN: 0959-8103
• DOI: 10.1002/(sici)1097-0126(199808)46:4<313::aid-pi30>3.0.co;2-y

✦ Synopsis

5-Bromopenta-1,3-diene (BPD) was examined as an additionfragmentation chain transfer agent (AFCTA) in the free radical polymerization of methyl methacrylate (MMA). Studies of the kinetics of polymerization in the presence of this compound showed it to be a very e †ective chain transfer agent and that retardation was not signiÐcant, implying efficient reinitiation by the expelled Br radical. Analysis of the resulting polymers showed that the intermediate radical formed by the addition of the propagating radical to the carbon C 1 of BPD underwent exclusive fragmentation. However, addition on the C 4 carbon, with a relative probability of 0É6, led to its copolymerization with MMA. Kinetic studies showed BPD to be a better chain-end functionalization agent than its 5-t-butyl thio derivative for deriving pentadiene-functional macromonomer.

1998 SCI.