Diffusion-controlled reactions in free radical polymerization—III: An estimate of the importance of geminate recombinations of radicals
✍ Scribed by C.R. Patrick; P.E.M. Allen
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- English
- Weight
- 400 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0014-3057
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract High‐resolution free radical polymerization kinetics was obtained using automatic continuous online monitoring of polymerization reactions (ACOMP). A sharp cross‐over from diffusion‐controlled initiation at low [monomer] to initiator decomposition control at higher [monomer] was found,
The role of monomer in catalytic chain transfer polymerization was studied by determination of the chain transfer constants of the tetraphenyl derivative of cobaloxime boron fluoride (COPhBF) in methyl methacrylate at 60 8C varying the monomer concentration instead of the COPhBF concentration as is