Modeling of diffusion-controlled free-radical polymerization reactions
β Scribed by D. Achilias; C. Kiparissides
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 956 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
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## Abstract The βlivingnessβ of a controlled radical polymerization process such as reversible additionβfragmentation transfer polymerization (RAFT) depends on the rapid deactivation of propagating radicals (the radical addition reaction in RAFT) that suppresses radical termination reactions. Howev
A kinetic model has been developed for stable free-radical polymerization (SFRP) processes by using the method of moments. This model predicts monomer conversion, number-average molecular weight, and polydispersity of molecular weight distribution. The effects of the concentrations of initiator, sta