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N,N′-Diphenyl­guanidinium 8-hydroxy­quinoline-5-sulfonate

✍ Scribed by Pereira Silva, P. S. ;Ramos Silva, M. ;Matos Beja, A. ;Paixão, J. A.


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
372 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the title compound, [Ag(C 9 H 6 NO 4 S)(H 2 O)]ÁH 2 O, the Ag I cation is three-coordinated by one N and one hydroxy O atom from one 8-hydroxyquinoline-5-sulfonate anion and one water molecule in a highly distorted trigonal-planar geometry. The sulfonate group does not coordinate to the Ag I cati

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The title mononuclear complex, [Ag(C 15 H 12 N 2 S) 2 ]CF 3 SO 3 , reveals the molecular symmetry C 2 with the Ag atom located on a crystallographic twofold axis. The Ag I centre is coordinated by two pyridine N-donors of two 8-(4pyridylsulfanylmethyl)quinoline ligands in an almost linear geometry.