Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.034 wR factor = 0.095 Data-to-parameter ratio = 14.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
N,N′-Diphenylguanidinium 8-hydroxyquinoline-5-sulfonate
✍ Scribed by Pereira Silva, P. S. ;Ramos Silva, M. ;Matos Beja, A. ;Paixão, J. A.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 372 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Á2C 9 H 6 SO 4 À ÁC 10 H 8 N 2 Á5H 2 O, the asymmetric unit contains two 8-hydroxyquinoline-5sulfonate (HQS) anions, two 4,4 H -bipyridinium ions, a neutral 4,4 H -bipyridine molecule and ®ve water molecules. The sulfonic acid group is deprotonated. Interestingly, in both the HQS anions, the OÐH bon
In the title compound, [Ag(C 9 H 6 NO 4 S)(H 2 O)]ÁH 2 O, the Ag I cation is three-coordinated by one N and one hydroxy O atom from one 8-hydroxyquinoline-5-sulfonate anion and one water molecule in a highly distorted trigonal-planar geometry. The sulfonate group does not coordinate to the Ag I cati
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.023 wR factor = 0.062 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title mononuclear complex, [Ag(C 15 H 12 N 2 S) 2 ]CF 3 SO 3 , reveals the molecular symmetry C 2 with the Ag atom located on a crystallographic twofold axis. The Ag I centre is coordinated by two pyridine N-donors of two 8-(4pyridylsulfanylmethyl)quinoline ligands in an almost linear geometry.