Aqua(8-hydroxyquinoline-5-sulfonato-κ2N,O8)silver(I) monohydrate
✍ Scribed by Wu, Hua ;Dong, Xian-Wu ;Ma, Jian-Fang
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 294 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Ag(C 9 H 6 NO 4 S)(H 2 O)]ÁH 2 O, the Ag I cation is three-coordinated by one N and one hydroxy O atom from one 8-hydroxyquinoline-5-sulfonate anion and one water molecule in a highly distorted trigonal-planar geometry. The sulfonate group does not coordinate to the Ag I cation.
📜 SIMILAR VOLUMES
A methanol solution (5 ml) of 8-hydroxyquinoline (0.075 g, 0.5 mmol) was mixed with an aqueous solution (5 ml) of AgNO 3
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.041 wR factor = 0.090 Data-to-parameter ratio = 17.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.023 wR factor = 0.062 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Zn 2 (C 9 H 4 INO 4 S) 2 (H 2 O) 6 ]Á4H 2 O, the coordination geometry around the Zn II atom is a distorted octahedron, formed by three water molecules, the N and deprotonated O atoms of the quinolinol ring and one of the O atoms of the sulfonate group. In the centrosymmetric