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Bis(μ-8-hydroxy-7-iodo­quinoline-5-sulfonato-κ3N,O:O′)­bis­[tri­aqua­zinc(II)] tetrahydrate

✍ Scribed by Francis, Savarimuthu ;Muthiah, Packianathan Thomas ;Bocelli, Gabriele ;Cantoni, Andrea

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
462 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Zn 2 (C 9 H 4 INO 4 S) 2 (H 2 O) 6 ]Á4H 2 O, the coordination geometry around the Zn II atom is a distorted octahedron, formed by three water molecules, the N and deprotonated O atoms of the quinolinol ring and one of the O atoms of the sulfonate group. In the centrosymmetric binuclear complex, there is a %±%-stacking interaction between the quinolinol rings. The water molecules of crystallization play an important role in the hydrogen-bonding patterns of the three-dimensional network.

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