𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis(4,4′-bipyridinium) bis(8-hydroxy­quinoline-5-sulfonate) bi­pyridine pentahydrate

✍ Scribed by Baskar Raj, Savarimuthu ;Muthiah, Packianathan Thomas ;Bocelli, Gabriele ;Cantoni, Andrea

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
278 KB
Volume
59
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

Á2C 9 H 6 SO 4 À ÁC 10 H 8 N 2 Á5H 2 O, the asymmetric unit contains two 8-hydroxyquinoline-5sulfonate (HQS) anions, two 4,4 H -bipyridinium ions, a neutral 4,4 H -bipyridine molecule and ®ve water molecules. The sulfonic acid group is deprotonated. Interestingly, in both the HQS anions, the OÐH bond is oriented away from the quinoline-N atom, since the water molecule competes in hydrogen bonding with the quinolinol-O atom. The neutral 4,4 H -bipyridine and one of the protonated 4,4 H -bipyridine moieties are bridged by two water molecules, resulting in a `U'-shaped hydrogen-bonded molecular arrangement. Many stacking interactions were observed between: (i) the pyridine rings of bipyridine moieties; (ii) the pyridine rings of bipyridine and HQS moieties; (iii) the pyridine ring of bipyridine and the benzene ring of the HQS anion.

📜 SIMILAR VOLUMES

4,4′-Bipyridinium bis(2-carboxy­benzene­
4,4′-Bipyridinium bis(2-carboxy­benzene­sulfonate) dihydrate
✍ Li, Xin-Hua ;Li, Zu-Guang ;Zhu, Yu-Qing 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 411 KB

## Figure 2 Perspective view of the molecular packing of (I), with hydrogen bonds shown as dashed lines.

(2,2′-Bi­pyridine)­bis(N-methyl-4,4′-bip
(2,2′-Bi­pyridine)­bis(N-methyl-4,4′-bipyridinium)­platinum(II) tetraperchlorate
✍ Sakai, Ken ;Osada, Manabu ;Yokoyama, Yoshimi ;Tomita, Yasushi ;Tsubomura, Taro 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 416 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.009 A Ê Disorder in solvent or counterion R factor = 0.047 wR factor = 0.126 Data-to-parameter ratio = 18.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis(2,2′-bi­pyridine)(3-carboxy-4-hydrox
Bis(2,2′-bi­pyridine)(3-carboxy-4-hydroxy­benzene­sulfonato)copper(II) 3-carboxy-4-hydroxy­benzene­sulfonate
✍ Gao, Shan ;Huo, Li-Hua ;Zhao, Hui ;Ng, Seik Weng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 224 KB

The Cu atom in the title compound, [Cu(C 7 H 5 O 6 S)-(C 10 H 8 N 2 )](C 7 H 5 O 6 S), is chelated by the two N-heterocycles and is covalently bonded to the sulfonate O atom of the sulfosalicylate ion in a trigonal±bipyramidal geometry. The uncoordinated sulfosalicylate anion interacts with adjacent

Bis[8-(4-pyridylsulfanylmethyl-κN)quinol
Bis[8-(4-pyridylsulfanylmethyl-κN)quinoline]silver(I) trifluoro­methane­sulfonate
✍ Song, Rui-Feng ;Wang, Yu-Hong 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 198 KB

The title mononuclear complex, [Ag(C 15 H 12 N 2 S) 2 ]CF 3 SO 3 , reveals the molecular symmetry C 2 with the Ag atom located on a crystallographic twofold axis. The Ag I centre is coordinated by two pyridine N-donors of two 8-(4pyridylsulfanylmethyl)quinoline ligands in an almost linear geometry.