N,N-Dimethyl-N'-phenylformamidinium perchlorate
✍ Scribed by Yogavel, M. ;Aravindan, P. G. ;Velmurugan, D. ;Perumal, P. T. ;Shanmuga Sundara Raj, S. ;Fun, H.-K.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 195 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.051 wR factor = 0.153 Data-to-parameter ratio = 18.9
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
phosphoric bis(4-methylbenzamide) dimethylamide], C 16 H 22 -N 3 OP, with tetrahedral phosphorus, are linked by twin NÐ HÁ Á ÁO [NÁ Á ÁO = 2.958 (3) A Ê ] hydrogen bonds into a linear chain.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.047 wR factor = 0.114 Data-to-parameter ratio = 21.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title vanadium complex, [VClO(C 16 H 22 N 4 )]ClO 4 , of the tetradentate ligand N,N H -dimethyl-N,N H -bis(2-pyridylmethyl)ethane-1,2-diamine was obtained from air oxidation of a mixture of the ligand and VCl 3 in wet methanol.
The title complex, C 21 H 21 N, crystallizes in space group P1, with Z = 6. The N atom is sp 2 -hybridized. The geometry of each of the three independent molecules is unremarkable. The interaction of the three molecules is discussed.