The title complex, C 21 H 21 N, crystallizes in space group P1, with Z = 6. The N atom is sp 2 -hybridized. The geometry of each of the three independent molecules is unremarkable. The interaction of the three molecules is discussed.
N,N-Dimethyl-N′,N′′-bis(4-methylphenyl)phosphoramidate
✍ Scribed by Gholivand, Khodayar ;Tadjarodi, Azadeh ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 244 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
phosphoric bis(4-methylbenzamide) dimethylamide], C 16 H 22 -N 3 OP, with tetrahedral phosphorus, are linked by twin NÐ HÁ Á ÁO [NÁ Á ÁO = 2.958 (3) A Ê ] hydrogen bonds into a linear chain.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.047 wR factor = 0.114 Data-to-parameter ratio = 21.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.051 wR factor = 0.153 Data-to-parameter ratio = 18.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 213 K Mean '(C±C) = 0.005 A Ê R factor = 0.062 wR factor = 0.181 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 133 K Mean '(C±C) = 0.002 A Ê R factor = 0.035 wR factor = 0.102 Data-to-parameter ratio = 23.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.