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[N,N′-Bis(6-methoxysalicylidene)-1,3-diaminopropane]copper(II)

✍ Scribed by Habibi, Mohammad Hossein ;Mokhtari, Reza ;Harrington, Ross W. ;Clegg, William


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
587 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, [Cu(C 19 H 20 N 2 O 4 )], is a mononuclear copper(II) Schiff base complex. The Cu II ion is surrounded by two imine N and two phenolate O atoms of the tetradentate ligand in a square-planar coordination with a slight tetrahedral distortion. The dihedral angle between the CuN 2 and CuO 2 planes is 25.07 (9) .

Related literature

A review of ligand environments and structures of Schiff base adducts and tetracoordinated metal chelates has been given by Garnovskii et al.


📜 SIMILAR VOLUMES


[N,N′-Bis(6-methoxysalicylidene)-1,3-dia
✍ Habibi, Mohammad Hossein ;Mokhtari, Reza ;Harrington, Ross W. ;Clegg, William 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 637 KB

The title compound (systematic name: {3,3 is isostructural with its Cu II analogue. The Ni II ion is coordinated within a distorted square-planar N 2 O 2 environment. The dihedral angle between the two NiNC 3 O chelate rings is 22.38 (12) .