[N,N′-Bis-(o-sulfidobenzylidene)-1,3-diaminopropane]nickel(II) 1,4-dioxane solvate
✍ Scribed by Taylor, Michelle K. ;Reglinski, John ;Wallace, Dawn
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 174 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [Ni(C 19 H 20 N 2 O 2 )], is mononuclear. The Ni II atom is four-coordinated in a square-planar configuration by two N atoms and two O atoms of the Schiff base ligand. The molecule possesses crystallographic mirror symmetry.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.036 wR factor = 0.107 Data-to-parameter ratio = 14.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 19 H 18 N 2 O 4 , the methyl group is disordered. The molecule is centrosymmetric and has a trans configuration (E,E).