N,N′-Bis(2-pyridylmethyl)ethane-1,2-diammonium dichloride hexadeuterodimethyl sulfoxide disolvate
✍ Scribed by Matiková-Maľarová, Miroslava ;Šebela, Marek ;Trávníček, Zdeněk
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 408 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title vanadium complex, [VClO(C 16 H 22 N 4 )]ClO 4 , of the tetradentate ligand N,N H -dimethyl-N,N H -bis(2-pyridylmethyl)ethane-1,2-diamine was obtained from air oxidation of a mixture of the ligand and VCl 3 in wet methanol.
{l-Bis [1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-j 2 N,N 0 0 0 }bis[iodo(triphenylphosphine-jP)copper(I)] acetonitrile disolvate
Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.003 A Ê Disorder in solvent or counterion R factor = 0.032 wR factor = 0.034 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
## Abstract The ligand __N,N′__‐bis(6‐methyl‐2‐pyridylmethyl)‐__N,N′__‐bis(2‐pyridylmethyl)ethane‐1,2‐diamine (L~6~^2^2M) has allowed to prepare the new Fe^II^ complex [(L~6~^2^2M)FeCl~2~] (1), and to compare its structural and spectroscopic characteristics with [(L~6~^2^2M)FeCl]PF~6~ (2). The mole
In the title compound, [Ni(C 23 H 18 N 3 O) 2 (H 2 O) 2 ]Á2C 2 H 6 OS, the Ni atom is octahedrally coordinated by two N atoms and two O atoms from two organic ligands and two water molecules which are cis to each other. The complex has crystallographic twofold rotation symmetry.