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Nickel(II) chloride adducts of 4′-phenyl-2,2′:6′,2″-terpyridine

✍ Scribed by Edwin C. Constable; David Phillips; Paul R. Raithby

Book ID
108495931
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
186 KB
Volume
5
Category
Article
ISSN
1387-7003

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✦ Synopsis

The reaction of 4 0 -phenyl-2,2 0 :6 0 ; 2 00 -terpyridine I with nickel(II) chloride gives a 1:1 adduct which we have structurally characterised and shown to be comprised of two species of stoichiometry fNiðIÞCl 2 g; the first is a five-coordinate [Ni(I)Cl 2 ] complex and the other is a dinuclear species containing two six-coordinate nickel centres [(I)ClNiðl-ClÞ 2 NiðIÞCl].

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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.009 A Ê R factor = 0.040 wR factor = 0.111 Data-to-parameter ratio = 14.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.