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[4′-(4-Aminophenyl)-2,2′:6′,2′′-terpyridine] chloridopalladium(II) chloride

✍ Scribed by Thomas, John C. (author);Tiekink, Edward R.T. (author);Walmsley, Judith A. (author)

Book ID
125542879
Publisher
International Union of Crystallography
Year
2011
Tongue
English
Weight
851 KB
Volume
67
Category
Article
ISSN
1600-5368

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The reaction of 4 0 -phenyl-2,2 0 :6 0 ; 2 00 -terpyridine I with nickel(II) chloride gives a 1:1 adduct which we have structurally characterised and shown to be comprised of two species of stoichiometry fNiðIÞCl 2 g; the first is a five-coordinate [Ni(I)Cl 2 ] complex and the other is a dinuclear s

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In the title molecule, C~22~H~17~N~3~O, the three pyridyl rings are almost coplanar. The molecule exhibits a __trans__–__trans__ arrangement of the pyridine rings about the interannular C—C bonds. The methoxyphenyl substituent makes a dihedral angle of 6.17 (7)° with the central pyridine ring.

Synthesis and luminescence properties of
Synthesis and luminescence properties of platinum(II) complexes of 4′-chloro-2,2′:6′,2″-terpyridine and 4,4′,4″-trichloro-2,2′:6′,2″-terpyridine
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The complex [Pt(Cl 3 terpy)Cl]PF 6 has been prepared from cis-[Pt(dimethylsulfoxide) 2 Cl 2 ] and 4,4%,4¦-trichloro-2,2%:6%,2¦-terpyridine (Cl 3 terpy). The complex [Pt(Clterpy)Cl]Cl has been prepared from cis-[Pt (1,5-cyclooctadiene)Cl 2 ] and 4%-chloro-2,2%:6%,2¦terpyridine (Clterpy). Complexes ha

4′-Nitro-2,2′:6′,2′′-terpyridine, 4′-Ami
4′-Nitro-2,2′:6′,2′′-terpyridine, 4′-Amino-2,2′:6′,2′′-terpyridine and Their Homo- and Heteroleptic Iron(II) and Ruthenium(II) Complexes
✍ Reza-Ali Fallahpour 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB 👁 1 views

The new ligands 4Ј-nitro-2,2Ј:6Ј,2ЈЈ-terpyridine and 4Ј-prepared and the electrochemistry of the complexes has been investigated. amino-2,2Ј:6Ј,2ЈЈ-terpyridine and their homoleptic and heteroleptic iron(II) and ruthenium(II) complexes have been 2,2Ј:6Ј,2ЈЈ-Terpyridine (tpy) is a versatile ligand for