[4′-(4-Aminophenyl)-2,2′:6′,2′′-terpyridine]chloridopalladium(II) chloride
✍ Scribed by Thomas, John C.; Tiekink, Edward R. T.; Walmsley, Judith A.
- Book ID
- 125542878
- Publisher
- International Union of Crystallography
- Year
- 2011
- Tongue
- English
- Weight
- 851 KB
- Volume
- 67
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The reaction of 4 0 -phenyl-2,2 0 :6 0 ; 2 00 -terpyridine I with nickel(II) chloride gives a 1:1 adduct which we have structurally characterised and shown to be comprised of two species of stoichiometry fNiðIÞCl 2 g; the first is a five-coordinate [Ni(I)Cl 2 ] complex and the other is a dinuclear s
In the title molecule, C~22~H~17~N~3~O, the three pyridyl rings are almost coplanar. The molecule exhibits a __trans__–__trans__ arrangement of the pyridine rings about the interannular C—C bonds. The methoxyphenyl substituent makes a dihedral angle of 6.17 (7)° with the central pyridine ring.
The complex [Pt(Cl 3 terpy)Cl]PF 6 has been prepared from cis-[Pt(dimethylsulfoxide) 2 Cl 2 ] and 4,4%,4¦-trichloro-2,2%:6%,2¦-terpyridine (Cl 3 terpy). The complex [Pt(Clterpy)Cl]Cl has been prepared from cis-[Pt (1,5-cyclooctadiene)Cl 2 ] and 4%-chloro-2,2%:6%,2¦terpyridine (Clterpy). Complexes ha
The new ligands 4Ј-nitro-2,2Ј:6Ј,2ЈЈ-terpyridine and 4Ј-prepared and the electrochemistry of the complexes has been investigated. amino-2,2Ј:6Ј,2ЈЈ-terpyridine and their homoleptic and heteroleptic iron(II) and ruthenium(II) complexes have been 2,2Ј:6Ј,2ЈЈ-Terpyridine (tpy) is a versatile ligand for