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6,6''-Dibromo-4'-phenyl-2,2':6',2''-terpyridine

โœ Scribed by Constable, E. C. ;Khan, F. K. ;Marquez, V. E. ;Raithby, P. R.


Book ID
114508993
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
318 KB
Volume
48
Category
Article
ISSN
0108-2701

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Nickel(II) chloride adducts of 4โ€ฒ-phenyl
โœ Edwin C. Constable; David Phillips; Paul R. Raithby ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 186 KB

The reaction of 4 0 -phenyl-2,2 0 :6 0 ; 2 00 -terpyridine I with nickel(II) chloride gives a 1:1 adduct which we have structurally characterised and shown to be comprised of two species of stoichiometry fNiรฐIรžCl 2 g; the first is a five-coordinate [Ni(I)Cl 2 ] complex and the other is a dinuclear s