In the title molecule, C~22~H~17~N~3~O, the three pyridyl rings are almost coplanar. The molecule exhibits a __trans__–__trans__ arrangement of the pyridine rings about the interannular C—C bonds. The methoxyphenyl substituent makes a dihedral angle of 6.17 (7)° with the central pyridine ring.
✦ LIBER ✦
2,2′:6′,4″-Terpyridine: a cyclometallating analogue of 2,2′:6′2″-terpyridine for metallosupramolecular chemistry
✍ Scribed by Edwin C. Constable; Alexander M.W. Cargill Thompson; Julian Cherryman(in part); Tracy Liddiment
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 610 KB
- Volume
- 235
- Category
- Article
- ISSN
- 0020-1693
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The complex [Pt(Cl 3 terpy)Cl]PF 6 has been prepared from cis-[Pt(dimethylsulfoxide) 2 Cl 2 ] and 4,4%,4¦-trichloro-2,2%:6%,2¦-terpyridine (Cl 3 terpy). The complex [Pt(Clterpy)Cl]Cl has been prepared from cis-[Pt (1,5-cyclooctadiene)Cl 2 ] and 4%-chloro-2,2%:6%,2¦terpyridine (Clterpy). Complexes ha