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Nickel, Palladium and Platinum Compounds

✍ Scribed by Carlos A. Murillo


Publisher
John Wiley and Sons
Year
2007
Weight
18 KB
Volume
38
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Nickel, Palladium a
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The 364-nm negative ion photoelectron spectra of XO and OXO molecules (X = Ni, Pd, and Pt) are reported. The spectra yield the electron affinities (EAs): EA(NiO) = 1.455 Β± 0.005 eV; EA(PdO) = 1.672 Β± 0.005 eV; EA(PtO) = 2.172 Β± 0.005 eV; EA(ONiO) = 3.043 Β± 0.005 eV; EA(OPdO) = 3.086 Β± 0.005 eV; EA(O

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A comparative study of the reactivity of the optically pure thioimine: (S C )-(-)-C 6 H 5 -CH=N-CH(CO 2 Me)-CH 2 -CH 2 -SMe (1) versus platinum(II) and palladium(II) salts is reported. The reaction of The absolute configuration of 3a has been established unambiguously by X-ray diffraction: orthorh