Platinum(II) and Palladium(II) Compounds Containing Chiral Thioimines

✍ Scribed by Xavier Riera; Concepción López; Amparo Caubet; Virtudes Moreno; Xavier Solans; Mercè Font-Bardia

• Publisher: John Wiley and Sons
• Year: 2001
• Tongue: English
• Weight: 430 KB
• Volume: 2001
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/1099-0682(200108)2001:8<2135::aid-ejic2135>3.0.co;2-2

✦ Synopsis

A comparative study of the reactivity of the optically pure thioimine:

(S C )-(-)-C 6 H 5 -CH=N-CH(CO 2 Me)-CH 2 -CH 2 -SMe (1) versus platinum(II) and palladium(II) salts is reported. The reaction of

The absolute configuration of 3a has been established unambiguously by X-ray diffraction: orthorhombic, with a = 8.979 ( ), b = 9.605( ), c = 18.205(6) A ˚, α = β = γ = 90.0°, space group P2 1 2 1 2 1 . Compound 3a contains a [6.5.6] tricyclic system generated by the fusion of a phenyl ring, a five-membered platinacycle and a six-membered chelate ring formed by the coordination of the [a]