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Nickel Complexes from α-Amino Amides as Efficient Catalysts for the Enantioselective Et2Zn Addition to Benzaldehyde.

✍ Scribed by M. Isabel Burguete; Manuel Collado; Jorge Escorihuela; Francisco Galindo; Eduardo Garcia-Verdugo; Santiago V. Luis; Maria J. Vincent

Book ID
101950361
Publisher
John Wiley and Sons
Year
2003
Weight
81 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

Nickel complexes from α-amino amides as
Nickel complexes from α-amino amides as efficient catalysts for the enantioselective Et2Zn addition to benzaldehyde
✍ M.Isabel Burguete; Manuel Collado; Jorge Escorihuela; Francisco Galindo; Eduardo 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 234 KB

Ni 2+ complexes derived from simple a-amino amides catalyze very efficiently the addition of Et 2 Zn to benzaldehyde, giving (S)-1-phenylethanol as the major isomer in most cases (94% yield, 97% ee for R=Bn). The nature of the substituent on the amide nitrogen atom seems to play a key role in determ

ChemInform Abstract: Chiral β- and γ-Ami
ChemInform Abstract: Chiral β- and γ-Aminoalcohols Derived from (+)-Camphor and (-)-Fenchone as Catalysts for the Enantioselective Addition of Diethylzinc to Benzaldehyde.
✍ Vladimir Dimitrov; Georgi Dobrikov; Miroslav Genov 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v