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New Supported β-Amino Alcohols as Efficient Catalysts for the Enantioselective Addition of Diethylzinc to Benzaldehyde under Flow Conditions

✍ Scribed by Burguete, M. Isabel; García-Verdugo, Eduardo; Vicent, María J.; Luis, Santiago V.; Pennemann, Helmut; Graf von Keyserling, Nikolai; Martens, Jürgen

Book ID
120280055
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
74 KB
Volume
4
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES

Chiral ferrocenyl amino alcohols as anal
Chiral ferrocenyl amino alcohols as analogues of norephedrine catalysts for enantioselective addition of diethylzinc to benzaldehyde
✍ Stéphanie Bastin; Jacques Brocard; Lydie Pélinski 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 146 KB

Optically active ferrocenyl amino alcohols have been prepared from commercially available l-alaninol and l-leucinol. They have been used in catalytic amounts as chiral ligands in the addition of diethylzinc to benzaldehyde. 1-Phenylpropanol has thus been obtained in up to 95% enantiomeric excess.

ChemInform Abstract: Chiral Ferrocenyl A
ChemInform Abstract: Chiral Ferrocenyl Amino Alcohols as Analogues of Norephedrine Catalysts for Enantioselective Addition of Diethylzinc to Benzaldehyde.
✍ Stephanie Bastin; Jacques Brocard; Lydie Pelinski 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

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