Ni 2+ complexes derived from simple a-amino amides catalyze very efficiently the addition of Et 2 Zn to benzaldehyde, giving (S)-1-phenylethanol as the major isomer in most cases (94% yield, 97% ee for R=Bn). The nature of the substituent on the amide nitrogen atom seems to play a key role in determ
✦ LIBER ✦
C2 symmetrical nickel complexes derived from α-amino amides as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes
✍ Scribed by Jorge Escorihuela; Belen Altava; M. Isabel Burguete; Santiago V. Luis
- Book ID
- 118162166
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- French
- Weight
- 546 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0040-4020
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v