[Ni(C4H13N3)2]3(Sb3S6)2: The First Structure Containing Isolated Heterocyclic [Sb3S6]3− Anions
✍ Scribed by Ragnar Kiebach; Felix Studt; Christian Näther; Wolfgang Bensch
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 127 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi
## Abstract As revealed by single crystal XRD compounds (II) and (VI) crystallize in the triclinic space group P$\bar 1$ with Z = 2, (IV) in the monoclinic space group P2~1~/m with Z = 4, and (V) in the monoclinic space group P2~1~/n with Z = 4.