The emission spectrum of VN has been investigated in the 3400-19 400 cm -1 region using a Fourier transform spectrometer. The bands were observed from the reaction of VOCl 3 vapor with active nitrogen. In addition to the previously known transitions of VN, several new bands observed in the visible a
NH(a1Δ → X3Σ−) emission from the gas-phase photolysis of HN3
✍ Scribed by F. Rohrer; F. Stuhl
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 393 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
During AC laser (IV3 nm) pllotolysis of11N3. a spcctrun~ of the emission from tlic Iiighly forbidden NH(a'A + X 3Z3 trmsition has beeri dctectcd. 13)' observing tile diuppcarance of this emission, tllc NH(a ' A) radicals were found to decay witli rates fxtcr than 33 s-l in tllis pllotolvsis s~stum. Rnte constants hnvc been estimated for tlte quenching by IINs. Ar.
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