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New Tripodal N3S Ligands and Some Zinc Complexes Thereof

✍ Scribed by Rainer Burth; Andreas Stange; Markus Schäfer; Heinrich Vahrenkamp

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
225 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis

Attachment of 2-pyridylmethyl units to cysteine amide and zinc perchlorate MBPA forms the ionic compound [L • Zn] ClO 4 , presumed to be a thiolate bridged dimer. Structure 2-mercaptobenzylamine leads to the new tripodal N 3 S ligands N α -(4-methylbenzoyl)-L-cysteine-bis(2-pyridylmeth-determinations of MBPA • ZnHal (Hal = Cl, Br) have confirmed the tripodal nature of the ligand in the trigonal-bipy-yl)amide (CBPA-H) and 2-mercaptobenzyl-bis(2-pyridylmethyl)amine (MBPA-H). Their treatment with zinc halides ramidal complexes. yields the neutral complexes L • ZnHal (Hal = Cl, Br, I). With

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