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New Tris(thioimidazolyl)borate Ligands and Some Zinc Complexes Thereof

✍ Scribed by Mohamed M. Ibrahim; Mouhai Shu; Heinrich Vahrenkamp

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
184 KB
Volume
2005
Category
Article
ISSN
1434-1948

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✦ Synopsis

Abstract

In order to improve the encapsulation of metal ions coordinated by tris(thioimidazolyl)borate ligands, four new such ligands with o‐substituted phenyl substituents were synthesised as well as ones with p‐tolyl and cyclohexyl substituents. In order to provide a basis for their bioinorganic zinc complex chemistry, they were converted to some zinc‐halide, ‐carboxylate, ‐nitrate, ‐phenolate and ‐benzylate complexes. They form zinc‐perchlorate complexes which are productive starting materials for the attachment of alcohols and alkoxides at zinc, thereby yielding new structural models for the zinc enzyme alcohol dehydrogenase. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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