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Zinc Complexes of Tripodal N3O Ligands

✍ Scribed by Alexander Trösch; Heinrich Vahrenkamp

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
533 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis

The tripodal N,O ligands bis(2-pyridylmethyl)(o-hydroxybenzyl)amine (L 1 ) and bis(2-pyridylmethyl)(2-carboxyethyl)amine (L 2 ) were tested for their ligating properties towards zinc. Zinc halides yielded L 1 •ZnϪHal (1aϪc, Hal = Cl, Br, I) and L 2 •ZnϪHal (2aϪc, Hal = Cl, Br, I). Subsequent treatment of L 1 with ZnEt 2 or Zn[N(SiMe 3 ) 2 ] 2 and phenol, thiophenols

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