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Application of N,S-Chelating Chiral Ligands and Zinc Complexes in Catalytic Asymmetric Hydrosilylation Using Polymethylhydrosiloxane.

✍ Scribed by Stephane Gerard; Yann Pressel; Olivier riant


Publisher
John Wiley and Sons
Year
2005
Weight
21 KB
Volume
36
Category
Article
ISSN
0931-7597

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Chiral Complexes of RhI Containing Binap
✍ Serafino Gladiali; Fabrizia Grepioni; Serenella Medici; Antonio Zucca; ZoltΓ‘n Be πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 137 KB

## Abstract The enantiopure complexes **3a** and **3b** [Rh(NBD)(P,S)]^+^BF~4~^βˆ’^ [P,S = (__S__)‐2‐(diphenylphosphanyl)‐2′‐(methylthio)‐1,1′‐binaphthalene (**a**); (__S__)‐2‐(diphenylphosphanyl)‐2′‐(isopropylthio)‐1,1′‐binaphthalene (**b**)] have been prepared from [Rh(NBD)(THF)~2~]^+^BF~4~^βˆ’^ by r