We give a general method for Ending the exact solution for the problem of electronic relaxation in solution, modelled by a particle undergoing diffusive motion in a potential in the presence of a delta function sink. The diffusive motion is described by the Smoluchowski equation and the sink could b
New results in the theory of barrierless electronic relaxation in solution
β Scribed by Biman Bagchi
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 462 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The effects of non-equilibrium solvation dynamics on zero-barrier photoisomerization reactions are studied theoretically. A theory based on general considerations is presented. A two-state model for the time dependence of the sink function is introduced and solved analytically for the survival proba
Different experimental techniques used to study dynamics of barrierless reactions have led to different results. An analysis of the cause of these differences is presented. In the absence of a clear separation of time scales between the reactive motion and the motion on the rest of the potential sur
## electronic relaxation We report a theoretical study oftransient behaviour ofbarrierless electronic reactions in solution. We havegeneralized theearly theory of Oster and Nishijima to the low-friction and small-time domain. An analytical form for the decay ofthe integrated excited state is deriv