✦ LIBER ✦

Transient behaviour of activationless electronic relaxation in solution

✍ Scribed by A.M. Jayannavar

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 314 KB
Volume: 199
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)80062-g

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✦ Synopsis

electronic relaxation

We report a theoretical study oftransient behaviour ofbarrierless electronic reactions in solution. We havegeneralized theearly theory of Oster and Nishijima to the low-friction and small-time domain. An analytical form for the decay ofthe integrated excited state is derived. We point out the strong friction and temperature dependence of the decay rate in the transient domain.

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