On the temperature dependence of the rate in barrierless reactions in solution
โ Scribed by Biman Bagghi
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 452 KB
- Volume
- 139
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The Arrhenius parameters of the bimolecular rate constants for the decay of several phenoxyl radicals in aqueous solution were measured. The p-halophenoxyl radicals (F, C1, and Br) decay in a diffusion controlled reaction as the activation energies are the same as that of diffusion of water (16 ? 1.
## Abstract The gelation kinetics in methylcellulose solutions of different concentrations is studied by DSC under rising temperature conditions. Isoconversional analysis reveals that the rate is a complex function of temperature represented by a concave downward dependence of the effective activat