✦ LIBER ✦

Effects of non-equilibrium solvation dynamics on barrierless electronic relaxation in solution

✍ Scribed by Biman Bagchi

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 437 KB
Volume: 135
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)85210-7

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✦ Synopsis

The effects of non-equilibrium solvation dynamics on zero-barrier photoisomerization reactions are studied theoretically. A theory based on general considerations is presented. A two-state model for the time dependence of the sink function is introduced and solved analytically for the survival probability of the excited state. Several interesting non-equilibrium solvation-induced effects which may be experimentally observable are predicted.

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