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Time-dependent solvation effects on the rate of nonradiative electronic relaxation in solution

✍ Scribed by Teresa Fonseca; Mário Cunha

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
457 KB
Volume
155
Category
Article
ISSN
0009-2614

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The effects of non-equilibrium solvation dynamics on zero-barrier photoisomerization reactions are studied theoretically. A theory based on general considerations is presented. A two-state model for the time dependence of the sink function is introduced and solved analytically for the survival proba