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Dependence of the true rate constant of homogeneous electron transfer on solvent relaxation time and viscosity

✍ Scribed by W. Harrer; G. Grampp; W. Jaenicke


Publisher
Elsevier Science
Year
1986
Weight
241 KB
Volume
209
Category
Article
ISSN
0022-0728

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The effect of solvent viscosity on the p
✍ Dietrich Tittelbach-Helmrich; Brian D. Wagner; Ronald P. Steer πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 421 KB

The S, population decay times of azulene and 4,6,8-trimethylazulene have been measured in solvents with a wide range of viscosities using a two-photon, two-color, pump-probe method. The S, lifetimes vary as expected on the basis of the energy gap law. No effect of solvent viscosity is observed, cont