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Solvent effect on the rate of homogeneous and electrochemical electron exchange

✍ Scribed by J. Wilson; O.Hwa Kai Ting; J. Lipkowski; A. Czerwinski


Publisher
Elsevier Science
Year
1988
Weight
875 KB
Volume
247
Category
Article
ISSN
0022-0728

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Effect of the dielectric saturation on t
✍ M. Tachiya πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 463 KB

Recently Kakitani and Mataga claimed that the free energy dependence of electron transfer rates in polar solvents could be explained by taking into account the dielectric saturation effect of polar solvents. It is shown that the basic assumption of their model is incorrect. The correct treatment of