A note on the evaluation of homogeneous cross-exchange electron-transfer rate constants
β Scribed by K.L.N. Phani; M.V. Sangaranarayanan
- Publisher
- Elsevier
- Year
- 1992
- Tongue
- English
- Weight
- 288 KB
- Volume
- 328
- Category
- Article
- ISSN
- 1572-6657
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The present work rests on non-adiabatic electron transfer theory. The influence of the molecular dynamics (MD) of exchanging groups on the electron transfer rate is treated. The MD of exchanging groups is described as a stochastic process with two possible states. The transfer between these two stat
Ah&act--The effect of bulk flow on mass transfer accompanied by homogeneous chemical reaction is discussed in terms of the film model. It is shown that at large concentration levels of the reacting species bulk flow due to diffusion may enhance the overall mass transfer rate, but this enhancement is