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New method for measuring the ratios of rate constants for radical recombination

✍ Scribed by Hiatt, R.; Benson, S. W.


Book ID
120175965
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
565 KB
Volume
94
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Rate constants for radical recombination
✍ R. Hiatt; S. W. Benson πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 English βš– 289 KB

Products of the radical reactions arising from t-BuZOz, CFsI, and CHsI at 146Β°C in the vapor phase have been measured over a 33-fold range of CHsI/CH,I ratios and shown to be governed by the rapidly established equilibrium Together with K estimated by thermochemical methods, the results yield, for

Rate constants for alkyl radical recombi
✍ R. Hiatt; S. W. Benson πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 English βš– 280 KB

Products of radical combination from the free-radical buffer system R' + R'I RI + R'. have been analyzed for the two cases, R = Me, R' = iPr and R = Et, R' = iPr. Results are consistent with the previously examined system where R = Me, R' = Et, and give a value of k p for iPr' combination of 108.6\

Yet another direct measurement of the ra
✍ F. C. James; J. P. Simons πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 194 KB πŸ‘ 1 views

## Abstract The decaying absorption of CH~3~ radicals at 216.4 nm has been followed over more than three half‐lives using a photoelectric split‐beam kinetic spectrometer. The rate constant for recombination __k__~r~ was found to be (5.60 Β± 0.76) Γ— 10^βˆ’11^ cm^3^/moleculeΒ·s.

The rate constant for the recombination
✍ A. B. Vakhtin πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 639 KB

The high-pressure rate constant of the CF, + CF, + C,F, reaction at T = 296 K was rneasured i n the pulse photolysis ( A = 694 3 nm ruby laser) of CF, NO in the presence of NO by means of the time-resolved detection of CF,NO by the intracavity absorption of He-Ne laser radiation ( A = 632 8 nrn) The