✍ Scribed by R. Gáspár; B. Koltay-Gyarmati
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The optical cm&ion resulting from collisicjns between Ct ions and Hq \_ gas was measured in the energy range 2 to 20 eVo,m . The observed spectrum consists \_zminly of the CH+A ITI -X Ix\* band system; CH+(A 'II) is shown to be formed' in the chemiluminescent reaction: 6(\*P"j + H2 -+ CH'(A 'II) f H
New high-level quantum chemical calculations have been undertaken to understand the rates and mechanisms of the reactive and associative channels for the reactants C2H2(+) + H2. The reactive channel, which produces C2H3(+) + H, has been shown to be slightly endothermic, confirming earlier calculatio
Ion-molecule reactions at very low energies (<lo-\* eV) are investigated quantum-mechanically, taking the reaction H-+H+H2 t e as an example. Quantum effects, the zero-energy limit of the cross section, and the validity of an orbiting model are examined. Tbe orbiting model is found to be satisfactor