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New initiator system for the living anionic polymerization of tert-alkyl acrylates

✍ Scribed by Fayt, R.; Forte, R.; Jacobs, C.; Jerome, R.; Ouhadi, T.; Teyssie, Ph.; Varshney, S. K.


Book ID
120443145
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
332 KB
Volume
20
Category
Article
ISSN
0024-9297

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## Abstract Potassium hydride with 1,4,7,10,13,16‐hexaoxacyclooctadecane (18‐crown‐6) was used in the anionic polymerization of (butoxymethyl)oxirane. Polymers with low ratio of mass‐ to number‐average molar masses (M̄~w~/M̄~n~ < 1.1) were obtained, each macromolecule being terminated (after hydrol