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Anionic Polymerization of Acrylates. Synthesis of (Meth)acrylate Di- and Triblock Copolymers Using the Li Ester−Enolate/ tert- Alkoxide Initiating System

✍ Scribed by Vlček, Petr; Otoupalová, Jaroslava; Janata, Miroslav; Látalová, Petra; Kurková, Dana; Toman, Luděk; Masař, Bohumil

Book ID: 126024101
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 102 KB
Volume: 37
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma035075c

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## Abstract In contrast to methyl 2‐lithioisobutyrate (I), __tert__‐butyl 2‐lithioisobutyrate (A) in tetrahydrofuran (THF) appears to have one form only, irrespective of concentration (0,1‐0,8 mol/L) or temperature (203–273 K). According to its relaxation characteristics, this form probably is a te