## Abstract Polystyrene‐__block__‐poly(methyl methacrylate) (PS‐__b__‐PMMA) has been synthesized by sequential anionic and reverse atom transfer radical polymerization (ATRP) or a variation of nitroxide mediated polymerization (NMP) from a single initiating site, specifically the 9‐carbon on 2,7‐di
✦ LIBER ✦
Synthesis of Meth(acrylate) Diblock Copolymers Bearing a Fluorescent Dye at the Junction Using A Hydroxyl-Protected Initiator and the Combination of Anionic Polymerization and Controlled Radical Polymerization
✍ Scribed by Tong, Jiang-Dong; Zhou, Chunlin; Ni, Shaoru; Winnik, Mitchell A.
- Book ID
- 120983592
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 126 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym